Should aquarium ammonia and nitrite be zero?
Zero is the usual target for both. Any detected amount deserves review, especially in a new aquarium, after filter disruption, or when fish are breathing hard or several fish are affected.
Why do pH and temperature change ammonia risk?
Total ammonia includes forms with different toxicity. A larger fraction can be present as more toxic un-ionized ammonia at higher pH and temperature, so one TAN number is not the whole picture.
Can normal readings rule out fish disease?
No. A snapshot can miss a recent spike, and disease, toxins, aggression, diet, and species-specific problems can occur even when the entered readings look broadly acceptable.
When are water parameters an emergency?
Low oxygen, suspected chlorine, extreme pH, significant ammonia or nitrite, and tank-wide gasping after a filter or water event can require immediate water-first action and experienced help.